Stephenson, D., Bevins, R.E., Millward, D., Highton, A.J., Parsons, I., Stone, P. & Wadsworth, W.J. 1999. Caledonian Igneous Rocks of Great Britain. Geological Conservation Review Series No. 17, JNCC, Peterborough, ISBN 1 86107 471 9. The original source material for these web pages has been made available by the JNCC under the Open Government Licence 3.0. Full details in the JNCC Open Data Policy
Loch Ailsh Intrusion
I. Parsons
Introduction
The Loch Ailsh intrusion
The intrusion was first described by Peach et al. (1907), who considered that it rests on a thrust (which they called the Sgonnan Beag Thrust). The petrology and internal structure were first described, in considerable detail, by Phemister (1926). Following a fashion of the time, he considered the intrusion to be a stratified laccolith, with a floor of dense pyroxenites. This interpretation did not survive later geophysical work (Parsons, 1965a), but the overall shape of the intrusion is still enigmatic. The age relationships of the Loch Ailsh and Loch Borralan intrusions are critical in understanding the relative and absolute timing of thrust movements in Assynt.
The igneous rocks are mainly sodium-rich alkali feldspar-syenites, for the most leucocratic of which Phemister (1926) coined the name 'perthosite'. Phemister subdivided the syenites into numerous named varieties (modern equivalents are given in parentheses): 'perthosite' (leucocratic alkali feldspar-syenite); aegirine-melanite syenite; 'nordmarkite' (quartz-syenite); 'pulaskite' (pyroxene syenite); riebeckite syenite; 'shonkinite' (pyroxene-rich syenite). Phemister's use of 'shonkinite' is not followed by more recent terminology, which requires the presence of nepheline. In contrast with Loch Borralan, feldspathoids are not found in the Loch Ailsh pluton. In addition, he recognized ultramafic biotite pyroxenites and hornblendites, similar (apart from the absence of garnet from the Loch Ailsh examples) to the 'cromaltites' described by Shand (1910) in the Loch Borralan complex, and drew attention to the similarity between them and the rock type 'jacupirangite' discovered in other alkaline complexes.
The pyroxene syenites occur chiefly as xenoliths enclosed in the leucosyenites, and form a discontinuous roof to the earlier syenite units, while the pyroxenites and hornblendites form a substantial, although poorly exposed vertical marginal body. These rocks occur between the more felsic intrusive rocks and Durness Group dolomitic limestones along the eastern margin, in a similar structural setting to the equivalent 'cromaltites' at Loch Borralan.
Halliday et al. (1987) obtained a U-Pb age of 439 ± 4 Ma on zircons from two samples of Loch Ailsh syenite, a little older than the age of 430 ± 4 Ma obtained for the Loch Borralan intrusion using the same method. Although the western contact of the Loch Ailsh mass is now only about 1 km east of the contact of the Loch Borralan intrusion
There is some disagreement over the age relationships between the Loch Ailsh intrusion and structures within the enclosing Ben More Nappe. Milne (1978) suggested on the basis of careful mapping that the intrusion was emplaced later than the earliest phase of deformation in Assynt, the Sgonnan Mór folding. However, Halliday et al. (1987) suggested that greenschist facies recrystallization in some xenolithic pyroxene syenites in the Loch Ailsh intrusion could be correlated with the Sgonnan Mór phase of folding.
The contact relationships of the Loch Ailsh intrusion, and its three-dimensional shape, are not easily defined. On Sgonnan Beag mylonitized syenite is seen against Cambrian quartzite (the Sgonnan Beag Thrust of Peach et al., 1907) but the plane of movement at the exposure dips steeply in a southerly direction rather than NE, beneath the intrusion. In the ground north of Loch Sail on Ruathair, in the unnamed stream that Phemister (1926) called the 'Metamorphic Burn'
In places, rocks of the Loch Ailsh intrusion are considerably deformed by late movements in the Moine thrust zone. Zones of mylonite occur at several localities and are well seen in the River Oykel
Description
The intrusion is about 10 km2 in area
Pyroxene syenites ('shonkinites' of Phemister, 1926) occur at localities in the River Oykel
Ultramafic biotite-magnetite pyroxenites and hornblendites, crop out in isolated localities along the eastern margin of the complex, along the Allt Cathair Bhàn
The isolated hillock known as Sròn Sgaile in the NE corner of the complex
Syenites
The leucocratic syenites were described in detail by Parsons (1965b). Units S2 and S3 are well exposed throughout the southern part of the complex. Si is less well exposed and crops out in Coire Sail an Ruathair. The most informative areas are those that show the inter-relationships between the units, and three critical exposures are of particular interest. At the base of the cliffs beneath the northern summit of the Sail an Ruathair ridge the junction between Si and S3 can be examined
S2–S3 relationships can be seen in the central part of the intrusion around the confluence of the Allt Sail an Ruathair and the River Oykel
Mineralogically, S1, S2 and S3 form an evolutionary series. The mafic mineral in most rocks is a pyroxene, those in S1 being diopsidic (calcium- and magnesium-rich), while those in S3 can have nearly 50 molecular % of the sodium-iron pyroxene component, aegirine; S2 is intermediate (Parsons, 1979). There are slight parallel changes in alkali feldspar composition, those in S1 being exceptionally rich in the albite molecule (c. 75 molecular %), those in S3 richer in orthoclase (c. 65 molecular % albite). Some facies, particularly of S2, contain a strongly pleochroic riebeckitic alkali amphibole instead of, or in addition to, pyroxene. Melanite garnet, often zoned and intergrown with titanite, appears only in the part of S3 that forms the southern summit on the Sail an Ruathair ridge
Pyroxene syenites — 'shonkinites'
The most important exposure of these rocks is in the River Oykel
Pyroxene syenites also occur as xenoliths in syenite in the Black Rock Burn
A screen, about 10 m thick, of laminated pyroxene syenite, similar to those seen in the southern part of the intrusion, occurs about halfway up the exposed section of the 'Metamorphic Burn'. As at the other localities, the rock occurs on the upper surface of a body of earlier syenite, in this case S1. There are numerous altered limestone xenoliths both above and below this locality. A 5 m-wide screen of dark-green pyroxenite, and some metre-scale smaller xenoliths, occur 100 m higher up the stream. These resemble the ultramafic clots found elsewhere in the pyroxene syenites. The lowermost screen (stratigraphically highest) is attached directly to a mass of metasedimentary rock representing the Fucoid Beds, whereas the uppermost xenolith is resting against a large mass of quartzite.
Ultramafic rocks
A suite of unusual diopside pyroxenites and hornblendites is exposed at isolated localities along the eastern edge of the complex in Allt Cathair Bhàn
The ultramafic rocks are deep blue-green biotite pyroxenites. They are often somewhat sheared, when the pyroxene is converted to a green-brown hornblende. The pyroxenes are close to pure diopside in composition (Parsons, 1979). Like the equivalent 'cromaltites' in the Loch Borralan intrusion, apatite is abundant, as is ilmenomagnetite, and the latter mineral leads to the very large local magnetic anomalies found over the pyroxenite members of both intrusions. The only worthwhile exposures are at
Metamorphic xenolithic rocks
An excellent suite of metamorphic xenolithic rocks occur in an unnamed stream (called the 'Metamorphic Burn' by Phemister, 1926) which flows into Loch Sail an Ruathair
A log of the stream bed, starting at the lowest exposures, which occur about 400 m above Loch Sail an Ruathair, was given by Parsons (1968). At the base there are many originally dolomitic xenoliths, now diopsidic and phlogopitic calc-silicate rocks. Mafic patches can be seen in the enclosing syenites, and at certain localities individual pyroxenes can be observed apparently in the process of incorporation into the syenite. At 170 m (measured along the ground from the lowest exposures) an unusual white, melanite garnet-bearing syenite seems to be related to a large limestone xenolith, and just above here is a thick screen of red syenite (S1). At 270 m a 3 m body of fine, flinty dark-green rock with conspicuous pink feldspars and dark minerals, in contact with white or dark-grey quartzite, represents the Salterella Grit of the Cambro-Ordovician succession. Slightly above, 20 m of baked grey shale, with black streaks, represents the Fucoid Beds. Immediately in contact is a 2 m mass of dark-green pyroxenite, with micaceous patches (a 'shonkinite' of Phemister, 1926). There are also two small xenoliths of altered dolomitic limestones; which must have been moved out of their stratigraphical position by the magma. From the 308 m point upwards the syenite (S3) contains massive quartzite xenoliths that include developments of alkali amphibole, an example of the metasomatic process of fenitization. Conspicuous red feldspar xenocrysts sometimes have their long axes aligned, dipping downstream, and there are xenoliths of red syenite (probably S2). The last exposures seen before the stream flows through drift are of a pink, riebeckite-bearing syenite, probably S2.
Interpretation
The overall form of the Loch Ailsh intrusion is difficult to establish because of poor exposure in the vicinity of the contacts. Evidence that it formed a thrust sheet in its own right, as proposed by the early Survey workers (Peach et al, 1907; Phemister, 1926), is not strong and it seems likely that the intrusion was emplaced in the Ben More Nappe either prior to the first folding phase in Assynt (as postulated by Halliday et al., 1987) or shortly after (as proposed by Milne, 1978). This relatively early emplacement has been confirmed by the radiometric age of 439 ± 4 Ma obtained by Halliday et al. (1987). The ages provided by the alkaline rocks in Assynt are crucial for dating movements in the Moine thrust belt. The Loch Ailsh rocks in places are deformed (mylonitized) by late movements on the Moine Thrust, and there is geophysical evidence that the eastern contact passes under the Moine. The interfingering of syenite with a largely undisturbed sequence of altered Cambro-Ordovician sedimentary rocks, in the 'Metamorphic Burn' is consistent with a relatively gentle style of emplacement into the rocks of the Ben More Nappe. There is no convincing evidence that the intrusion is a stratified laccol-ith, as proposed by Peach et al. (1907) and Phemister (1926), although the late syenite unit S3 appears to overlie one or other of the earlier S1 and S2 units over much of the intrusion suggesting that S3 has a sheet-like form.
The eastern contact, along which a screen of pyroxenites is interposed between syenite and Durness Group dolomitic limestones, is certainly sub-vertical but the magnetic anomalies that lead to this conclusion give little information on the vertical extent of the intrusion. Like the similar pyroxenites along the southern margin of the Loch Borralan intrusion the origin of these rocks is enigmatic. The pyroxenites in the latter intrusion are definitely intrusive into quartzites and therefore certainly existed as a magma, but there are no exposures at Loch Ailsh that demonstrate that the pyroxenites have an intrusive character. It is curious that in both intrusions the pyroxenites occur only where silicate rocks and dolomitic limestone are in contact. There is no easy explanation for the extended sinuous form of the pyroxenite body if it is entirely intrusive. If it is earlier than the syenites as the cross-cutting veins of syenite superficially suggest, then it is possible that it is an incomplete section of an earlier, arcuate intrusion; alternatively if the syenite veins result from rheomorphism then it is a partial ring dyke. Whatever its structural relationships, the high temperature mineralogy requires that the pyroxenites were emplaced as a crystal mush; there is no direct evidence that they are mobilized cumulate rocks formed in situ from the syenite magma, as suggested by Matthews and Woolley (1977) for Loch Borralan, although this is a possible mode of origin.
The syenitic rocks were emplaced in three pulses. They were fractionated before arrival in their final resting place, and become chemically more evolved and peralkaline with time. Both the earlier members (S1 and S2) form dome-shaped bodies overlain by a final unit mostly composed of very leucocratic alkali feldspar-syenite ('perthosite', S3). The slightly more mafic, aegirine- and melanite-bearing variant forming the South Top of Sail an Ruathair is the most highly evolved member. More melanocratic, pyroxene syenites occur as xenolithic blocks at various localities; these seem to appear discontinuously on the upper surface of the earlier syenite units and perhaps represent a disrupted roof, a view supported by the sporadic appearance of metasedimentary xenoliths at the same level. The pyroxene syenites have textural and chemical similarities to syenites demonstrably (in the 'Metamorphic Burn') modified by partial assimilation of altered dolomitic limestone. While on the one hand some of the pyroxene syenites have thoroughly igneous textures, there is also strong textural evidence of assimilation of material of metasedimentary origin. Perhaps the pyroxene syenites represent an early phase of igneous activity itself modified by reactions with the sedimentary envelope. Major element chemistry, mineral chemistry and even trace-element chemistry are equivocal on this subject (Parsons, 1979; Young et al., 1994).
Conclusions
The Loch Ailsh intrusion includes a suite of sodic syenites unique in the British Isles, which provide evidence for igneous fractionation processes before emplacement, and include the world type locality for 'perthosite'. The pyroxenites of the eastern margins are extremely enigmatic rocks whose extent and subsurface shape have been elucidated by geophysical means. A suite of intermediate, pyroxene syenites include rocks that have a thoroughly igneous appearance as well as types that have certainly formed by reactions between the syenite magma and dolomitic sedimentary rocks from the envelope. There are very instructive exposures illustrating contact metamorphism, alkali metasomatism (fenitization) and assimilation of a large range of Cambro-Ordovician sedimentary rocks. The structural relationships of the Loch Ailsh body, and its known age of 439 Ma, provide an important age-marker for movements in the Moine thrust zone.